Ask An Expert 31010
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I have a problem with ammonia violations at some of my small (less than 7,500 gallons/day) extended aeration package wwtp’s that I contract operate. These plants are designed to remove an influent ammonia level in the range of 25 mg/l. However, after testing the influents at some of these small plants, I have found the influent levels to be in excess of 100 mg/l.
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Lonnie Mcghee
President, MTWSi
2230 James Road
Bellville, Ohio 44813
Phone/fax (419) 886-4716
Cell: (419) 565-8975
e-mail: mtwsi@aol.com
What is your position/area of expertise?
President/Owner, 30 years operators experience
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Answer #1 |
Lonnie, I would like to refer you for assistance from my Ohio EPA DSW Technical Assistance Group who have previously done a lot of work advising ODOT with compliance problems at their small Rest Stop package plants. these small plants have very high ammonia-urine rich slightly acidic influents. I believe they worked to add chemical addition to buffer the pH to allow the nitrifiers to get back in their happy zone.
Ohio EPA Keith Kroeger
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Answer #2
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I think that Keith summarized this pretty well. I agree with his suggestion to run this question by the OEPA, DSW, TAG. I will add a few
1) Both TKN and ammonia should be measured to see how much nitrogen is in organic form.
2) pH < 7 SU hinder the maximum rate of substrate conversion for nitrification. The idea pH would be about 7.8 to 8.5 SU, and below 6.5 SU, the nitrogen greately slows or stops. Also, nitrifiers are temperature sensitive. The theta value, if I recall, is about 1.06.
3) Nitrifiers are strict autotrophs, which require a highly oxic environment both inside the floc and in bulk liquid. The maximum rate for substrate conversion occurs at DO > 3.0 mg/l. DO greater than 4 mg/l adds little and wastes energy. Also, being strict autotrophs, nitrifiers lack the ability to store food for subsequent conversion, which means that they have to "eat what they see" at the time. This is unlike hetrotrophs, which have a storage feature - which is why contact stabilization works to convert CBOD5. As a result, temporal variations in concentration will cause substrate bleed through and effluent violations.
4) These factors point to the need to have a well sized bioreactor system, with adequate DO, provisions to add a source of alkalinity, and a great need for load equalization througout the day. I think that load equalization and possible bleed through during peak periods may be a factor.
5) Also, there is a possibility that short circuiting may be occurring.
6) Alkalinity in the final effluent needs to be above 100 mg/l CaCO3 to avoid pH suppression.
7) I agree that having a trash trap ahead of a package plant is a great source of unknowns and should not be done if possible. It adds too much variability. The dilemma is finding very small screens that can work in very low flow environments. However, as a former OEPA employee, I saw more "dead" communitors than "live" ones.
8) One final word: Please make sure that there is enough carbon available in the wastestream to complete the denitrification process.
While soda ash will help balance pH, there is a possibility that there is not enough carbon to complete the nitrification process at certain times of the day.
In thinking further, effort should be made to inventory cleaning agents as they may behave as toxicants if introduced in inappropriate mass loadings.
Nitrifiers are sensitive and can be hurt easily.
Good Luck, Dale E. Kocarek, PE, BCEE |
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